Tel: 021-54743472
Email: chenzhimin221@sjtu.edu.cn
Address: 上海市东川路800号大阳城集团72138官网建工楼322A室,邮编:200240
Home Page: https://www.x-mol.com/groups/Chen_Zhimin323
Education
2009-2014 Ph.D. in Organic Chemistry with Professor Yong-Qiang Tu
College of Chemistry and Chemical Engineering, Lanzhou University, China
2005-2009 B.S. in Chemistry
College of Chemistry and Chemical Engineering, Fuzhou University, China
Working Experience
2015-2017 Postdoctoral Researcher with Professor Matthew S. Sigman
Department of Chemistry, University of Utah, USA
2014-2017 Postdoctoral Research Assistant with Professor Yong-Qiang Tu
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, China
Fields of Interests
Asymmetric Catalysis, Chiral Sulfur and Selenide Chemistry, Total Synthesis of Natural Products
主持国家自然科学面上项目(2项)、青年基金(1项,已结题)、上海市教委(1项)、大阳城集团72138官网启动经费,功能有机分子化学国家重点实验室开放课题(2021-2023)。
Recent Publications
16. Kai Ji, Ka Lu, Jie Huang, Zi-Hao Li, Hua Ke*, Zhi-Min Chen*
Brønsted Acid-Catalyzed Regioselective Hydrothiolation of Dienes: Solvent-Controlled Divergent Synthesis of Sulfides
Org. Lett. 2021, 23, 8028-8032.
15. Yu-Yang Xie, Yun-Peng Wang, Xiao-Jing Zhao, Ai-Fang Wang, Zhi-Min Chen*, Yong-Qiang Tu*.
Oxyallyl Cation Promoted Dearomative Semipinacol Rearrangement: Facile Stereodivergent Synthesis of Spiro-indolines with Contiguous Quaternary Centers
Chem. Commun., 2021, 57, 6632-6635.
14. Deng Zhu, Ai-Hui Ye, Zhi-Min Chen*
N-Selenocyanato-dibenzenesulfonimide: a new electrophilic selenocyanation reagent (Feature Article, invited submission)
Synthesis 2021, DOI: 10.1055/a-1493-6885
13. Deng Zhu, Hui-Yun Luo, Zhi-Min Chen*
Selenium-Catalyzed Trifluoromethylsulfinylation/Rearrangement of Allylic and Propargylic Alcohols: Access to Allylic and Allenic Triflones
Org. Lett. 2021,23, 1044-1048.
12. Deng Zhu, Tong-Mei Ding, Hui-Yun Luo, Hua Ke, Zhi-Min Chen*
Divergent Synthesis of Trifluoromethyl Sulfoxides and β-SCF3 Carbonyl Compounds by Tandem Trifluoromethylthiolation/Rearrangement of Allylic and Propargylic Alcohols
Org. Lett. 2020, 22, 7699-7703.
11. Xu-Feng Song, Tong-Mei Ding, Deng Zhu, Jie Huang, Zhi-Min Chen*
Lewis-Acid-Mediated Intramolecular Trifluoromethylthiolation of Alkenes with Phenols: Access to SCF3‑Containing Chromane and Dihydrobenzofuran Compounds
Org. Lett. 2020, 22, 7052-7056.
10. Chao-Chao Xi, Xiao-Jing Zhao, Jin-Miao Tian*, Zhi-Min Chen*, Kun Zhang, Fu-Min Zhang, Yong-Qiang Tu*, and Jia-Wei Dong
Atroposelective Synthesis of Axially Chiral 3-Arylindoles by Copper-Catalyzed Asymmetric Cross-Coupling of Indoles with Quinones and Naphthoquinones
Org. Lett. 2020, 22, 4995-5000.
9. Yu-Yang Xie, Zhi-Min Chen,* Hui-Yun Luo, Hui Shao, Yong-Qiang Tu,* Xiaoguang Bao,* Ren-Fei Cao, Shu-Yu Zhang, Jin-Miao Tian
Lewis Base/Brønsted Acid Cocatalyzed Enantioselective Sulfenylation/Semipinacol Rearrangement of Di- and Trisubstituted Allylic Alcohols
Angew. Chem. Int. Ed. 2019, 58, 12491-12496.
Featured by Benjamin List, Joyce A. A. Grimm in SYNFACTS 2019, 15, 1175.
8. Hui-Yun Luo, Jia-Wei Dong, Yu-Yang Xie, Xu-Feng Song, Deng Zhu, Tongmei Ding, Yuanyuan Liu,* Zhi-Min Chen *
Lewis Base/Brønsted Acid Co-catalyzed Asymmetric Thiolation of Alkenes with Acid-Controlled Divergent Regioselectivity
Chem. Eur. J. 2019, 25, 15411-15418.
7. Hui-Yun Luo, Yu-Yang Xie, Xu-Feng Song, Jia-Wei Dong, Deng Zhu, Zhi-Min Chen *
Lewis base-catalyzed asymmetric sulfenylation of alkenes: construction of sulfenylated lactones and application to the formal syntheses of (-)-nicotlactone B and (-)-galbacin
Chem. Commun., 2019, 55, 9367-9370.
6. Ai-Hui Ye, Ye Zhang, Yu-Yang Xie, Hui-Yun Luo, Jia-Wei Dong, Xiao-Dong Liu, Xu-Feng Song, Tongmei Ding, Zhi-Min Chen*
TMSCl-Catalyzed Electrophilic Thiocyano Oxyfunctionalization of Alkenes Using N-Thiocyano-dibenzenesulfonimide
Org. Lett., 2019, 21, 5106-5110.
5. Xu-Feng Song,† Ai-Hui Ye,† Yu-Yang Xie, Jia-Wei Dong, Chao Chen, Ye Zhang,* Zhi-Min Chen* (†equal contribution)
Lewis Acid Mediated Thiocyano Semipinacol Rearrangement of Allylic Alcohols for the Construction of α-Quaternary Center β-Thiocyano Carbonyls
Org. Lett., 2019, 21, 9550-9554.
4. Chao Chen, Jun-Chen Kang, Chen Mao, Jia-Wei Dong, Yu-Yang Xie, Tong-Mei Ding, Yong-Qiang Tu, Zhi-Min Chen*, Shu-Yu Zhang*
Electrochemical Halogenation/Semi-pinacol Rearrangement of Allylic Alcohols Using Inorganic Halide Salt: An Eco-friendly Route to Synthesis of β-halocarbonyls
Green Chem., 2019, 21, 4014-4019. (Inside front cover)
3. Jun-Chen Kang, Yong-Qiang Tu, Jia-Wei Dong, Chao Chen, Jia Zhou, Tong-Mei Ding, Jian-Tao Zai, Zhi-Min Chen*, Shu-Yu Zhang*.
Electrochemical semipinacol rearrangements of allylic alcohols: construction of all-carbon quaternary stereocenters.
Org. Lett., 2019, 21, 2536–2540. (Most downloaded)
2. Jia‐Wei Dong, Tongmei Ding, Shu‐Yu Zhang*, Zhi‐Min Chen*, Yong‐Qiang Tu*.
A Facile Approach to Oximes and Ethers by a Tandem NO+‐Initiated Semipinacol Rearrangement and H‐Elimination.
Angew. Chem. Int. Ed. 2018, 57, 13192-13196.
1. Chao-Chao Xi, Zhi-Min Chen*, Shu-Yu Zhang, Yong-Qiang Tu*.
Electrophilic Trifluoromethylthiolation/Semipinacol Rearrangement: Preparation of β-SCF3 Carbonyl Compounds with α-Quaternary Carbon Center.
Org. Lett., 2018, 20, 4227–4230.
Prior to SJTU:
1. Zhi-Min Chen†, Jianbo Liu†, Jing-Yao Guo, Maximilian Loch, Ryan Deluca, Matthew S. Sigman* (†equal contribution)
Palladium-catalyzed enantioselective alkenylation of alkenylbenzene derivatives
Chem. Sci., 2019, 10, 7246-7250
2. Zhi-Min Chen, Christine S. Nervig, Ryan J. DeLuca, and Matthew S. Sigman*. Palladium-catalyzed enantioselective redox-relay Heck alkynylation of alkenols to access propargylic stereocenters
Angew. Chem. Int. Ed. 2017, 56, 6651-6654.
3. Zhi-Min Chen, Margaret J. Hilton, and Matthew S. Sigman*.
Palladium-catalyzed enantioselective redox-relay Heck arylation of 1,1-disubstituted homoallylic alcohols
J. Am. Chem. Soc. 2016, 138, 11461-11464.
4. Zhi-Min Chen,† Xiao-Ming Zhang†, and Yong-Qiang Tu* (†equal contribution). Radical aryl migration reactions and synthetic applications
Chem. Soc. Rev. 2015, 44, 5220-5245.
5. Zhi-Min Chen, Zhen Zhang, Yong-Qiang Tu,* Ming-Hui Xu, Fu-Min Zhang, Chen-Chen Li, and Shao-Hua Wang*.
A Mn(III)/TEMPO-co-mediated tandem azidation/1,2-carbon migration reaction of allylic silyl ethers
Chem. Commun. 2014, 50, 10805-10808.
6. Zhi-Min Chen, Wei Bai, Shao-Hua Wang, Bin-Miao Yang, Yong-Qiang Tu,* and Fu-Min Zhang.
Copper-catalyzed tandem trifluoromethylation/semipinacol rearrangement of allylic alcohols
Angew. Chem. Int. Ed. 2013, 52, 9781-9785.
7. Zhi-Min Chen, Bin-Miao Yang, Zhi-Hua Chen, Qing-Wei Zhang, Min Wang, and Yong-Qiang Tu*.
Organocatalytic asymmetric fluorination/semipinacol rearrangement: An efficient approach to chiral β-fluoroketones
Chem. Eur. J. 2012, 18, 12950-12954.
8. Zhi-Min Chen, Qing-Wei Zhang, Zhi-Hua Chen, Hui Li, Yong-Qiang Tu,* Fu-Min Zhang, and Jin-Miao Tian.
Organocatalytic asymmetric halogenation/semipinacol rearrangement: highly efficient synthesis of chiral α-oxa-quaternary β-haloketones
J. Am. Chem. Soc. 2011, 133, 8818-8821.
Research Opportunities
Candidates with asymmetric catalysis, organometallic chemistry or organic synthesis background are welcomed to apply. If you are interested, please feel free to contact me anytime and send your CV to chenzhimin221@sjtu.edu.cn.
本科生:《大学化学》《有机化学实验》
研究生:《现代有机合成》
授权中国发明专利4项。
Honors & Awards
1. Postdoctoral Fellowship from Shanghai Jiao Tong University (2015-2017)
2. National Scholarship for Graduate Students, China (2013)
3. National Scholarship for Graduate Students, China (2012)
4. “Tang Au-Chin” Chemistry Scholarship (2012)
5. The 5th “Hanyu Scholarship” for Graduate Students (2012)
6. Outstanding Undergraduate Graduation Thesis, Fuzhou University, China (2009)
Address:800 Dongchuan RD. Minhang District, Shanghai, China
PostCode:200240 Tel:021-54742893 E-mail:sjtuscce@sjtu.edu.cn
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